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18 April 2008

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Your issue here is fuel. When a candle melts, it produces enough fuel to make the candle not fizzle out, the same thing can be said of the butter, your fat content in the butter becomes your fuel for your flame. So if you want to make a water-based gel that will not fizzle out you will need to add some fuel to it, the easier being fat. In theory, if you can make your gel filled with pockets of fat, it would normally rise to the top and become your fuel, and still melt the rest of your water-based gel melt under it. The devil is in the proportions, which I have no idea what it could be. I doubt that a full emulsion would work though, although I could be wrong...

Hm. Candles work because the wax melts and wicks up the wick via capilary action, where it then burns. Any water would need to evaporate off before it wicks up and smothers the flame. I don't think an alcohol-based solution would work very well, as alcohol would evaporate before the water, not after it. So you're stuck with a mixture of an oil and a little water, like the butter you did before. If you use an oil that's solid at room temperature, you can do what you've done. You could try to emulsify a sauce that's 75-25 fat:water, gel it, and see if that works. Could you emulsify and gel an oil-heavy vinaigrette, maybe, and use that? You could use a concentrated vinegar to get the flavor with less water, maybe.

Interesting problem! And you haven't even mentioned the bits of cotton ash in your sauce!

Fats, waxes and oils are all types of lipids, catagorised by the temperature at which they become liquid.

In the case of wax, as the wick burns it melts the fat below it and draws it up towards the flame, allowing the flame to carry on burning. This is why the butter candle worked too. As butter is a lipid it is hydrophobic and so doesn't mix with water - again - this is why the butter candle burned.

Unfortunately, you've got to be careful what you use for your wick - you don't want the burning of the wick to cause any bad flavours/chemicals.

Also, candles are a fairly inefficient method of burning, and as a result there is alot of incomplete combustion. For example, hold a plate over the flame of a burning candle and soon the plate will be covered in soot. This is carbon which hasn't bee burned properly due to a lack of oxygen reaching the flame. If you leave a candle burning long enough the black soot collects in the pool surrounding the bottom of the flame - something which again could harm the flavour/customer

With the hydrocolloids you are using to set the candle, you also have to make sure that they're safe for consumption once they are burned.

Why not try using tapioca maltodextrin to make a 'dry' candle from a particular fat. The resulting powder could be compressed and may melt properly when exposed to heat.
http://www.playingwithfireandwater.com/foodplay/2008/04/powders.html

Alternatively, alcohol burns, so maybe try making a candle out of a hydrocolloid and a strong-ish alcohol - although - that might be a bit too flammable

Fascinating idea...i really liked the idea of the sauce being created before your eyes...but having dealt with lawyers (long story), i can assure you that having diners pouring a flammable liquid with a flame, would terrify the lawyers representing the restaurant, and delight plantiff's lawyer's (when a tipsy patron pours the flammable stuff on themselves).

All that said, i look forward to reading about your creations!

From what I can remember from highschool chem and digging around on the internet, what's going on in the reaction of a candle is that your initial match is igniting the fuel that is infused in the wick. The combustion releases significant heat which melts the solid-state fuel in the candle, which then travels up the wick and there is a separation process in which hydrogen is burned in one part of the flame and carbon (released from CO2) is burned in another part of the flame (this is why a candle flame is multi-colored).

In your experiment, it sounds like you aren't providing enough or the right kind of solid-state fuel to continue the recurring thermal reaction. Water (H2O) doesn't burn because of extremely strong hydrogen bonds. Butter, on the other hand, burned because of the glycerol that is vaporized and ignited at the fire point (I might be off the mark with that one...I haven't looked into the structure of butter fat specifically). Anyways, what matters to your project is creating a sustainable solid-state fuel source to continue your thermal reaction. This fuel might be completely separate from the actual "sauce". I'd bet that the rosemary-butter sauce for the lamb was a mixture of rosemary oil and certain butter fats that don't break down as quickly as others (so while one set of fats was burning, the others were just liquefying and mixing).

As for whether or not your different gels specifically are ignitable, that's something I've never thought of/looked into...though now I'm really intrigued.

And recalled that for centuries candles were made out of tallow, refined beef fat. Refined pork fat is just lard and will do basically the same thing.

This is a really interesting read if you can stomach the language: http://www.gutenberg.org/etext/14474

How was your original butter candle made? Did you literally stick a wick (wax covered or bare?) into a cylinder of butter?

What about ethanol?

Problem is, unless segregated (or a small percentage), the water component of a sauce will put out the flame. Ethanol burns and is water-compatible, but I doubt you want your sauce to be almost pure alcohol, and you're likely to have the whole thing set on fire as opposed to just the wick.

Maybe try using another lipid like olive oil. It's liquid at room temperature, so maybe you could either 1) cool it until it solidified and allow the flame and ambient temperature to liquefy it at the table or 2) make something like an olive oil mousse/mayo and see if making that into a candle would allow it to melt.

One thing you'd have to watch out for, though, is oxidation and burnt flavor-- olive oil is sensitive. If that doesn't do well maybe try something with a higher smoke point or use a lighter olive oil (i.e. non-virgin).

Hmm... just thought of something. I'm not sure how to do it, but if you could hydrogenate the oil then it would solidify at room temp.

Also, cocoa butter is solid at room temperature and has a high smoke point. Maybe try that...

this is so cool, what a visionairy(sp?) I cannot wait to see the results :)

For a candle to burn, you definitely need a lipid to burn, be it a wax, fat or oil (all pretty much the same thing, chemically speaking). There's no reason you couldn't gel a flavoured sauce and get it to burn as long as it had a high fat concentration (80% or more, butter is roughly 85% lipids), but there might be another way.

Given you don't need the candle to burn for hours, what you could do is get your wick, and make a slender dip-candle from, say, lard or butter (something solid at room temperature) by dipping the wick into the melted fat, then chilled water, back into the fat, etc. until you've built up a sufficiently thick layer. Then mount this edible candle in the centre of a second gelled sauce so that as the candle burns and the fat melts the two flavours can combine. Maybe integrate a flavoured oil into the candle (rosemary, thyme, truffle)? It'd definitely need some experimentation, but would overcome the need to have a really oil based sauce for the entire candle.

Do you think a foie gras candle would work? Or just a foie fat candle?

If we disregard edibility, I would try ethanol (>50% ethanol) together with agar. Agar forms a gel with pretty large pores, so perhaps a wick would be able to suck out som ethanol. However, even though agar is heat stable I doubt that it would survive for long once the flame comes close to the surface. There is a chance that the whole thing will startburning, but I guess if you get the water/ethanol mix right, the solid agar will not burn.

I'm skipping to the bottom since i've been out of the loop for the last two weeks with the impending beard dinner. I don't know if anyone threw this out there or not but what about the use of alcohol in your candle? How about an au poivre candle? Cracked pepper, brunoise shallot, cognac, a gelled cream? Or soakng the wick in alcohol? This could help keep the flame going, possibly.

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